Dude, I just seen your build thread and realized you have your car already completely disassembled.... and that it is a wagon. So there are three other control points I wanted to give you insight on.
First, as you noted there is already a factory sound deadener. All automotive manufacturers do this to some varying degree. But it is a compromise of cost, weight, performance. Look at it this way, if you're buying a Lexus instead of a Toyota, or a Cadillac instead of a Chevy. One of the added costs is more sound deadener, and the research on where to put it. By no means will they ever stop all sounds. But from low-end to high-end there is good, better and best. I'm not super familiar with Mercedes line up, but I would assume yours falls in the middle. Which brings me to my second Control point.
One simple way to lower road noise from the factory is use "mass loaded vinyl backed" carpet. All carpets have a plastic backing, but this would be an extra layer that is still part of the carpet. If your car has that, I would consider not lining the floor as the product is already there. Which brings me to the third control.
Being a wagon is inherently going to bring more road noise in from the rear tires . That would definitely be a place I would personally Focus on.
Here are a few pointers on controlling panel resonation. Pack butyl rope between the body and support rods anywhere there is a support bar inside of the structural body of the car. Second is tap each body panel with your hand or a small tool, to find the areas that have the highest resonation. Install the CDL tiles there first, then wash, rinse, repeat. This way you can get the tiles were they are most needed.
As far as heat, that is a tough one. Unfortunately what you are battling is probably more a product of humidity than actual temperature. Where I live is dryer than a motherfucker, you would come here and think 100° feels like 70°. Not to say that the heat barrier is not possibly good idea, but it will definitely be a lot less effective where you live. I say it's worth a little more research, as I am no thermodynamics expert.
No need to thank me as I enjoy helping others, so pass the favor along. I just hate seeing people do more work then they need to. One way I gauge intelligence is the ability to use ones resources and energy wisely.